Carbon capture and storage
Type of resources
Contact for the resource
This poster on the UKCCSRC Call 2 project, Measurement of water solubility limits of CO2 mixtures to underpin the safe pipeline transportation of CO2, was presented at the Cranfield Biannual, 21.04.15. Grant number: UKCCSRC-C2-185.
This poster on the UKCCSRC Call 2 project UK Demonstration of Enhanced Calcium Looping and first Global Demonstration of Advanced Doping Techniques was presented at the CSLF Call project poster reception, London, 27.06.16. Grant number: UKCCSRC-C2-209. Calcium (carbonate) looping is a promising carbon capture technology, which has been successfully demonstrated using a slip stream from the exhaust of a large-scale power plant. CO2 is captured as CaCO3, and is then calcined to release a pure stream of CO2 suitable for storage. The main advantage of this cycle is that the exothermic CO2 capture stage takes place around 650°C and the heat released in the carbonation process can be used in a standard steam cycle. The aims of this project are: • To demonstrate the viability of enhanced calcium looping technologies for CCS using a pelletized spent lime stream. • To demonstrate the viability of calcium looping for the removal of CO2 from industrial gases (steel and iron industry and cement industry). • To explore the use of enhanced Ca looping using HBr as doping agent.
The solubility of water (H2O) in carbon dioxide (CO2) and nitrogen (N2) mixtures (xN2 = 0.050 and 0.100, mole fraction) has been investigated at 25 and 40 degrees C in the pressure range between 8 and 18 MPa. The motivation for this work is to aid the understanding of water solubility in complex CO2-based mixtures, which is required for the safety of anthropogenic CO2 transport via pipeline for carbon capture and storage (CCS) technology. The measurements have been performed using an FTIR spectroscopic approach and demonstrate that this method is a suitable technique to determine the concentration of water in both pure CO2 and CO2 + N2 mixtures. The presence of N2 lowers the mole concentration of water in CO2 by up to 42% for a given pressure in the studied conditions and this represents important data for the development of pipelines for CCS. This work also provides preliminary indications that the key parameters for the solubility of H2O in such CO2 + N2 mixtures are the temperature and the overall density of the fluid mixture and not solely the given pressure of the CCS mixture. This could have implications for understanding the parameters required to be monitored during the safer transportation of CO2 mixtures in CCS pipelines. The paper is available at http://www.sciencedirect.com/science/article/pii/S1750583615000444, DOI: 10.1016/j.ijggc.2015.02.002. UKCCSRC Grants UKCCSRC-C1-21 and UKCCSRC-C2-185.
Fiscal metering could face several challenges during CO2 transport by pipelines due to the unusual physical properties of CO2 and CO2 mixtures. Coriolis flowmeters are an options to measure CO2 accurately in transport pipelines. However, the presence of impurities can affect the performance of the flowmeter. Therefore, the performance of a Coriolis flowmeter was evaluated using CO2 fluid with impurities in a mass flow-rig designed based on the gravimetric calibration in start / stop operations. In each test, the mass recorded by the Coriolis flowmeter was compared to the mass collected in the receiving facilities and measured using high accurate balance in order to obtain the relative deviation of the test. During the tests, in addition to the mass and volume flow rate, the operational pressure and temperature as well as velocity and density were recorded. The series of tests were conducted using different fluids, including: pure N2 (validation tests), pure CO2 (reference tests), pre-combustion mixture, post-combustion mixture, Oxyfuel-I mixture and Oxyfuel-II mixture. The recorded data as well as recorded and measured masses are available in the provided excel files for each investigated fluid. Grant number: UKCCSRC-C2-201
Dupont, Valerie (2016) Data for "Kinetics study and modelling of steam methane reforming process over a NiO/Al2O3 catalyst in an adiabatic packed bed reactor" in International Journal of Hydrogen Energy. University of Leeds. Data file containing datasets used to generate the figures and tables in the paper. [Dataset] https://doi.org/10.5518/126. [Publication] http://doi.org/10.1016/j.ijhydene.2016.11.093
This Microsoft Excel document contains 5 worksheets providing data produced by research as part of UKCCSRC Call 1 funded project (grant number UKCCSRC-C1-31) and UKCCSRC funded international exchange. These data are presented and discussed in the manuscript "Geochemical tracers for monitoring offshore CO2 stores" by J. Roberts, S. Gilfillan, L. Stalker, M. Naylor, https://doi.org/10.1016/j.ijggc.2017.07.021. Then data details the assumptions around background concentrations of chemical tracers in the atmosphere and seawater, cost per litre, and how tracer detection concentrations (and so cost and potential environmental impact were calculated).
The spreadsheet gathers the data collected during two experiments conducted on a synthetic sandstone core sample to assess geophysical monitoring techniques, storage capacity evaluation and the geomechanical integrity of shallow CO2 storage reservoirs. The tests were conducted in the rock physics laboratory at the National Oceanography Centre, Southampton, during 2016, as part of the DiSECCS project with funding from the United Kingdom's Engineering and Physical Sciences Research Council (EPSRC grant EP/K035878/1) and the Natural Environment Research Council (NERC). One experiment was a steady state brine-CO2 flow-through test (so called BTFT in the spreadsheet) to simultaneously evaluate storage capacity and identify pore fluid distribution and mechanical indicators during CO2 geosequestration. The confining and pore pressure conditions were similar to those estimated for shallow North Sea - like storage reservoirs, but simulating inflation/depletion cyclic scenarios for increasing brine:CO2 fractional flow rates. The second experiment focused on the assessment of geomechanical changes (the so called GAT in the spreadsheet) during and after CO2 storage activities under the same stress conditions. The data include ultrasonic P- and S-wave velocities and their respective attenuation factors and axial and radial strains in both tests, and electrical resistivity in the case of the flow-through test.
Data derived from UKCCSRC Call 2 Project C2-181. The journal article can be found at https://doi.org/10.1016/j.ijhydene.2017.05.222. The sorption enhanced steam reforming (SE-SMR) of methane over the surface of 18 wt. % Ni/Al2O3 catalyst and using CaO as a CO2-sorbent is simulated for an adiabatic packed bed reactor. The developed model accounts for all the aspects of mass and energy transfer, in both gas and solid phase along the axial direction of the reactor. The process was studied under temperature and pressure conditions used in industrial SMR operations. The simulation results were compared with equilibrium calculations and modelling data from literature. A good agreement was obtained in terms of CH4 conversion, hydrogen yield (wt. % of CH4 feed), purity of H2 and CO2 capture under the different operation conditions such as temperature, pressure, steam to carbon ratio (S/C) and gas mass flux. A pressure of 30 bar, 923 K and S/C of 3 can result in CH4 conversion and H2 purity up to 65% and 85% respectively compared to 24% and 49% in the conventional process.
This presentation on the EPSRC project, CONTAIN, was presented at the Cranfield Biannual, 21.04.15. Grant number: EP/K036025/1.
The IEA (International Energy Agency) Weyburn Carbon Dioxide (CO2) Monitoring and Storage Project has analysed the effects of a miscible CO2 flood into a carbonate reservoir rock at an onshore Canadian oilfield. Anthropogenic CO2 is being injected as part of an enhanced oil recovery operation. The European research was aimed at analysing longterm migration pathways of CO2 and the effects of CO2 on the hydrochemical and mineralogical properties of the reservoir rock. This report is a synthesis of the principal findings of the European research effort and an assessment of how successfully the project objectives have been met. http://nora.nerc.ac.uk/3682/.