These plagioclase and clinopyroxene mineral chemical and Sr isotope data come from Unit 10, Rum Layered Suite, NW Scotland. They underpin a publication entitled 'Rapid crystallisation of precious metal-mineralised layers in mafic magmatic systems', to be published in Nature Geoscience in 2020.
Direct geological observations made during field work, tied to positional information collected by hand-held GPS.
Core description, core samples and thin sections of Lower Carboniferous dolomite. Thesis : Reservoir Properties of Lower Carboniferous Limestone of the Derbyshire East Midlands Platform by Jack Stacey. Thesis: Advances in understanding the evolution of diagenesis in carboniferous carbonate platforms: insights from simulations of palaeohydrology, geochemistry, and stratigraphic development by Miles Frazer
The UK Government has set targets for the reduction of CO2 emissions of 80 % by 2050. Post-combustion capture of CO2 from power plants is key if we are to achieve these targets. Post-combustion CO2 capture is challenging due to the low concentration of CO2 in the waste stream and the presence of impurities (H2O, NOx, SOx, etc). Post-combustion capture adds energetic cost via the requirement to capture and compress the CO2. Amine-based scrubbing processes are being evaluated for post-combustion CO2 capture. This is a costly process, and the amines are corrosive. Other candidate technologies include physical adsorption into solid sorbents coupled with pressure-swing or temperature-swing adsorption/desorption. In principle this may lower the energy overhead, but the volume of sorbent required is extremely large, limiting the range of sensible materials. Membrane-based processes have potential advantages over the above. In particular, there are no losses due to heat required to regenerate and release CO2 from the spent sorbent or solvent, and the footprint for the technology and amount of material required is comparatively small. Here, we will develop advanced mixed matrix membranes (MMMs) technology utilising organic fillers, rather than inorganic fillers, that could be cost-effectively fitted to power plants to separate and capture CO2. There has been much research on inorganic-organic MMMs, using fillers such as zeolites and MOFs. However, it is challenging to achieve a homogeneous dispersion of the inorganic filler particles in the polymer matrix. This is exacerbated by the lack of compatibility between most fillers, which are frequently crystalline inorganic or metal-organic materials, and the membrane polymers, which are invariably amorphous and organic. We build therefore on our unique report of organic-organic MMM (Angew Chem Int Ed, 2013) , where excellent dispersion of the organic filler was found and there was good adhesion between the organic polymer and the organic filler, both of which are predominantly aromatic structures. We address this by bringing together two UK groups who have pioneered in the development of novel porous membranes (Budd) and new microporous organic materials (Adams, Cooper). Grant number: EP/M001342/1.
Experimental mechanical data for single crystal shear experiments. Grant abstract: In 2011, NERC began a scoping exercise to develop a research programme based around deep Earth controls on the habitable planet. The result of this exercise was for NERC to commit substantial funding to support a programme entitled "Volatiles, Geodynamics and Solid Earth Controls on the Habitable Planet". This proposal is a direct response to that call. It is widely and generally accepted that volatiles - in particular water - strongly affect the properties that control the flow of rocks and minerals (their rheological properties). Indeed, experiments on low-pressure minerals such as quartz and olivine show that even small amounts of water can weaken a mineral - allowing it to flow faster - by as much as several orders of magnitude. This effect is known as hydrolytic weakening, and has been used to explain a wide range of fundamental Earth questions - including the origin of plate tectonics and why Earth and Venus are different. The effect of water and volatiles on the properties of mantle rocks and minerals is a central component of this NERC research programme. Indeed it forms the basis for one of the three main questions posed by the UK academic community, and supported by a number of international experts during the scoping process. The question is "What are the feedbacks between volatile fluxes and mantle convection through time?" Intuitively, one expects feedbacks between volatiles and mantle convection. For instance, one might envisage a scenario whereby the more water is subducted into the lower mantle, the more the mantle should weaken, allowing faster convection, which in turn results in even more water passing into the lower mantle, and so on. Of course this is a simplification since faster convection cools the mantle, slowing convection, and also increases the amount of volatiles removed from the mantle at mid-ocean ridges. Nevertheless, one can imagine many important feedbacks, some of which have been examined via simple models. In particular these models indicate a feedback between volatiles and convection that controls the distribution of water between the oceans and the mantle, and the amount topography created by the vertical movement of the mantle (known as dynamic topography). The scientists involved in the scoping exercise recognized this as a major scientific question, and one having potentially far reaching consequences for the Earth's surface and habitability. However, as is discussed in detail in the proposal, our understanding of how mantle rocks deform as a function of water content is remarkably limited, and in fact the effect of water on the majority of mantle minerals has never been measured. The effect of water on the flow properties of most mantle minerals is simply inferred from experiments on low-pressure minerals (olivine, pyroxenes and quartz). As argued in the proposal, one cannot simply extrapolate between different minerals and rocks because different minerals may react quite differently to water. Moreover, current research is now calling into question even the experimental results on olivine, making the issue even more pressing. We propose, therefore, a comprehensive campaign to quantify the effect of water on the rheological properties of all the major mantle minerals and rocks using a combination of new experiments and multi-physics simulation. In conjunction with 3D mantle convection models, this information will allow us to understand how the feedback between volatiles and mantle convection impacts on problems of Earth habitability, such as how ocean volumes and large-scale dynamic topography vary over time. This research thus addresses the aims and ambitions of the research programme head on, and indeed, is required for the success of the entire programme.
The mechanical data (confining and injection pressures) recorded during Vickers indentation experiments on samples of shale materials. These experiments were conducted on the I12 beamline, Diamond Light Source, Harwell as part of beamtime EE17606-1 between 31/01/18 and 05/02/18.
The dataset comprises: Petrophysical data for rocks from the region, XRD mineralogical data, Results of the gravity survey of the basin, tabulation and location of all bedding orientation data for the basin, and sediment transport lineation data. The dataset accompanies publication : On the Structure and Evolution of the Sorbas Basin, S.E. Spain, Tectonophysics 773 (2019) 228230, DOI: https://doi.org/10.1016/j.tecto.2019.228230
This presentation on the EPSRC project, Organic Mixed Matrix Membrane Technologies (ORGMEMT) for Post-Combustion CO2 Capture, Cranfield Biannual, was presented at the Cranfield Biannual, 21.04.15. Grant number: EP/M001342/1.
This dataset represents the raw reads from sequencing the V4 hyper-variable region of the 16S rRNA gene on an Illumina MiSeq platform. The samples are filtered groundwater samples from 8 boreholes from a sandy-dominated site and a clay-dominated site in Cambodia that show arsenic concentrations above the WHO recommended limit, and were collected in May 2019.
This dataset comprises unprocessed microprobe analyses (WDS) of 10-15 natural zeolite samples, using the method of Campbell et al. (2016), and relating to the hypothesis of Campbell et al. (2012). Minerals analysed include stilbite, chabazite, phillipsite and harmotome. Key localities include the Western USA (oregon) and Europe (Germany and Scotland). Published papers and abstracts.