A possible effect of a carbon dioxide leak from an industrial sub-sea floor storage facility, utilised for Carbon Capture and Storage, is that escaping carbon dioxide gas will dissolve in sediment pore waters and reduce their pH. To quantify the scale and duration of such an impact, a novel, field scale experiment was conducted, whereby carbon dioxide gas was injected into unconsolidated sub-sea floor sediments for a sustained period of 37 days. During this time pore water pH in shallow sediment (5 mm depth) above the leak dropped >0.8 unit, relative to a reference zone that was unaffected by the carbon dioxide. After the gas release was stopped, the pore water pH returned to normal background values within a three-week recovery period. Further, the total mass of carbon dioxide dissolved within the sediment pore fluids above the release zone was modelled by the difference in DIC between the reference and release zones. Results showed that between 14 and 63% of the carbon dioxide released during the experiment could remain in the dissolved phase within the sediment pore water. This is a publication in QICS Special Issue - International Journal of Greenhouse Gas Control, Peter Taylor et. al. Doi:10.1016/j.ijggc.2014.09.006.

A two-fluid, small scale numerical ocean model was developed to simulate plume dynamics and increases in water acidity due to leakages of CO2 from potential sub-seabed reservoirs erupting, or pipeline breaching into the North Sea. The location of a leak of such magnitude is unpredictable; therefore, multiple scenarios are modelled with the physiochemical impact measured in terms of the movement and dissolution of the leaked CO2. A correlation for the drag coefficient of bubbles/droplets free rising in seawater is presented and a sub-model to predict the initial bubble/droplet size forming on the seafloor is proposed. With the case studies investigated, the leaked bubbles/droplets fully dissolve before reaching the water surface, where the solution will be dispersed into the larger scale ocean waters. The tools developed can be extended to various locations to model the sudden eruption, which is vital in determining the fate of the CO2 within the local waters. This is a publication in Marine Pollution Bulletin, Marius Dewar et. al. doi:10.1016/j.marpolbul.2013.03.005.

Carbon capture and storage (CCS) is a way of possibly reducing impacts from fossil fuel emissions by injecting large volumes of carbon dioxide into appropriate geological formations. Some of the existing and proposed storage sites are below the seabed. In order to better understand the environmental impacts of leaks from a sub-surface marine storage facility and to investigate how leaks or potential leaks could be detected, a world-first experiment consisting of an artificial carbon dioxide release from below the seabed was undertaken in 2012. The need for accurate deployments and re-deployments of measurement equipment, the retrieval of biological and sediment samples within very specific areas of the release site and the in-situ measurement of escaping gas volumes, necessitated an extensive scientific diving program. Diving was also employed to determine the most optimum experimental site prior to the program’s initiation and to map the site prior to the beginning of the experiment. Diving also proved to be an essential tool (through observation, photography and videography) in recording the progress of the experiment and the physical interactions and impacts arising from managing a large multi-partner, multi-discipline research program. This is a publication in Diving for Science 2014: Proceedings of the American Academy for Underwater Sciences 33rd Symposium, Martin D.J. Sayer et. al. http://www.aaus.org/uploads/protected/files/publications/symposium_proceedings/diving_for_science_2014.pdf

Carbon capture and storage is a mitigation strategy that can be used to aid the reduction of anthropogenic CO2 emissions. This process aims to capture CO2 from large point-source emitters and transport it to a long-term storage site. For much of Europe, these deep storage sites are anticipated to be sited below the sea bed on continental shelves. A key operational requirement is an understanding of best practice of monitoring for potential leakage and of the environmental impact that could result from a diffusive leak from a storage complex. Here we describe a controlled CO2 release experiment beneath the seabed, which overcomes the limitations of laboratory simulations and natural analogues. The complex processes involved in setting up the experimental facility and ensuring its successful operation are discussed, including site selection, permissions, communications and facility construction. The experimental design and observational strategy are reviewed with respect to scientific outcomes along with lessons learnt in order to facilitate any similar future. This is a publication in QICS Special Issue - International Journal of Greenhouse Gas Control, Peter Taylor et. al. Doi:10.1016/j.ijggc.2014.09.007.

The dataset details global positioning system (GPS) locations recorded for survey quadrats at six UK saltmarsh sites. Three of the sites were in Morecambe Bay, North West England and three of the sites were in Essex, South East England, each of these sites consisted of a salt marsh area and adjacent mudflat area. Each site comprised 22 quadrats on the unvegetated mudflat and 22 quadrats on the salt marsh. The locations indicated by this dataset correspond to the south-east corner of the quadrats which were 1m square and oriented with their sides aligned North-South and East-West. We combined spatial data relating to the environs of the study sites from a number of sources (Ordnance Survey Digital Terrain Models, Ordnance Survey Boundary Line, Environment Agency Saltmarsh Extents, Natural England Priority Habitat Inventory). These were rasterised and quadrat values were extracted on a pointwise basis for elevation and proximity (distance to creek, habitat edge and high water mark). Tidal height was calculated with reference to the relevant Tidal Gauge and Admiralty Standard Port information. This data was derived as part of Coastal Biodiversity and Ecosystem Service Sustainability (CBESS): NE/J015644/1. The project was funded with support from the Biodiversity and Ecosystem Service Sustainability (BESS) programme. BESS is a six-year programme (2011-2017) funded by the UK Natural Environment Research Council (NERC) and the Biotechnology and Biological Sciences Research Council (BBSRC) as part of the UK's Living with Environmental Change (LWEC) programme. Full details about this dataset can be found at https://doi.org/10.5285/78a2cab5-dca5-411b-ac5b-c2c080928b1d

The dataset comprises 82 hydrographic data profiles, collected by a conductivity-temperature-depth (CTD) sensor package, from across the North Atlantic Ocean area specifically the Ellett line CTD stations from Sound of Mull to Rockall, on the Wyville Thomson Ridge and in the Minch. The data were collected during July and August of 2003. A complete list of all data parameters are described by the SeaDataNet Parameter Discovery Vocabulary (PDV) keywords assigned in this metadata record. The data were collected by the Scottish Association for Marine Science as part of the Northern Seas Programme (NSP).

The dataset comprises 15 hydrographic data profiles, collected by a conductivity-temperature-depth (CTD) sensor package, from across the North East Atlantic Ocean (limit 40W) area specifically the shelf seas to the west of Scotland, during June and July of 2009. A complete list of all data parameters are described by the SeaDataNet Parameter Discovery Vocabulary (PDV) keywords assigned in this metadata record. The data were collected by the Scottish Association for Marine Science as part of the Oceans 2025 programme.

The Fluxes Across Sloping Topography of the North East Atlantic (FASTNEt) data set comprises a diverse collection of oceanographic (largely physical and chemical) observations, together with model simulation output. FASTNEt data were collected from three principal localities in close proximity to the UK’s Shelf Edge – the Celtic Sea, the Malin Shelf and the North Scotland Shelf. Each of these were chosen for contrasting bathymetric properties and associated slope current characteristics. There were two main research cruises associated with FASTNEt. These took place in the summers of 2012 and 2013. The core observations include measurements of temperature, salinity, nutrients, currents and shear harvested from a suite of instrumentation including CTDs, ocean gliders (as well as other Autonomous Underwater Vehicles), drifter buoys and moored sensors. The FASTNEt data set aims to develop new parameterisations of shelf edge exchange processes, which will benefit future ocean modelling and forecasting exercises. Additional observations were made from moored instrumentation and autonomous platforms (including ocean gliders, AUVs and drifter buoys) adding to the temporal and spatial coverage of the core cruise data sets. The FASTNEt data set was compiled in order to improve understanding of the processes of physical and biogeochemical exchange at shelf edge margins. These margins are important gateways for the supply of nutrients to our shallow shelf seas, with implications for biodiversity and fishery resources. The NERC FASTNEt Consortium brings together scientists from various UK research centres including the Scottish Association for Marine Science (SAMS), National Oceanography Centre (NOC) and the Universities of Bangor, Liverpool and Plymouth.

This multi-decadal time series initially contains water current and temperature data from a single, near bottom instrument. A second, shallower instrument recording the same parameters was subsequently added after several years of successful operation. Conductivity data are similarly integrated into the time series after a further period of operation. The data are typically at hourly resolution. The mooring is situated in the Tiree Passage, between the Isles of Mull and Coll, off the west coast of Scotland. The specific site chosen was where the passage is at its narrowest (10 km), mid-way between the coasts of the two Isles. The mooring site is in water depths of approximately 45 m. Mooring activity began in June 1981 and consisted of a single RCM current meter placed 11 m above the seabed. The mooring design was modified to incorporate a second RCM current meter at 22 m above the seabed from November 1987. Aanderaa conductivity sensors were added at the two depths in 1993, with MicroCAT conductivity sensors being incorporated in 2002. There are some gaps in the record, most noticeably between January 2000 and May 2002, a period when the observations were temporarily suspended. Fishing damage has generated smaller gaps in the data set over the years. This region was chosen as a site for long term monitoring after radiocaesium studies showed that the major part of the water carried northwards from the North Channel in the Scottish coastal current passes between Mull and Coll. The mooring provides data for comparison with tracer studies and for an examination of the roles of wind forcing and buoyancy contributions to the coastal current. Tiree Passage mooring work is led by Colin Griffiths at the Scottish Association for Marine Science (SAMS).

The dataset comprises 75 hydrographic data profiles, collected by a conductivity-temperature-depth (CTD) sensor package, from across the Norwegian Sea area specifically along and across the West Spitsbergen Shelf during August and September 2005. A complete list of all data parameters are described by the SeaDataNet Parameter Discovery Vocabulary (PDV) keywords assigned in this metadata record. The data were collected by the Scottish Association for Marine Science as part of the Northern Seas Programme (NSP).