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IDA267644 Methane and CO2 gas concentrations and stable isotope analyses of select core samples from GGC01 borehole of the Glasgow UKGEOS facility. Core samples were collected approximately every 10m depth in gas tight isojars by the BGS. Geochemical gas analyses was carried out at the Scottish Universities Environmental Research Centre (SUERC) and consisted of bulk concentration analysis using gas chromatography; followed by δ13CCH4, δ13CCO2, and δD stable isotope analyses on a methane combustion line (full methods attached). This data was collected to investigate the variability of gas fingerprints with depth within the Glasgow coal mine workings, and unmined Carboniferous coal measures. Samples and data are derived from the UK Geoenergy Observatories Programme funded by the UKRI Natural Environment Research Council and delivered by the British Geological Survey.
IDA272269 Methane and CO2 gas concentrations and stable isotope analyses of cutting samples from GGA05 and GGA08 boreholes of the Glasgow UKGEOS facility. Cutting samples were collected approximately every 3m depth in gas tight isojars by the BGS. Geochemical gas analyses was carried out at the Scottish Universities Environmental Research Centre (SUERC) and consisted of bulk concentration analysis using gas chromatography; followed by δ13CCH4, δ13CCO2, and δD stable isotope analyses on a methane combustion line (full methods attached). This data was collected to investigate the variability of gas fingerprints with depth within the Glasgow coal mine workings, and unmined Carboniferous coal measures. Samples and data are derived from the UK Geoenergy Observatories Programme funded by the UKRI Natural Environment Research Council and delivered by the British Geological Survey.
[This dataset is embargoed until July 1, 2025]. This dataset contains information about the compound-specific stable hydrogen isotope composition (δ2H) of n-alkanoic acids with 26, 28 and 30 carbon atoms. The samples originated from the Lake Suigetsu sediment cores. Data is provided at an approximately ~60 year resolution from 132.7 ka BP to 125.2 ka BP (n = 60). To accompany this data, the mass-normalised concentrations of key n-alkane and n-alkanoic acids are provided, alongside n-alkane index values. This data was collected to infer changes to the Lake Suigetsu catchment and the East Asian Summer Monsoon during Glacial Termination II. This work was supported by the Quaternary Research Association, the Scottish Alliance for Geoscience, Environment and Society, the School of Geographical and Earth Science (University of Glasgow) and the NERC IAPETUS2 Doctoral Training Partnership. Full details about this dataset can be found at https://doi.org/10.5285/e3ebeca1-ce57-40f9-8237-85d8aa543ff8
The dataset worksheet contains a list of core samples taken during IODP Exp 350 and foraminifera-based data for selected samples. The work was started with the aim of reconstructing palaeoproductivity changes (namely surface-to-deep carbon isotope gradients and U/Ca measurements) over tephra layers in order to test the ‘ash fertilisation hypothesis’. However, the work has been temporarily halted given the on-board volcanologists ongoing concerns that the ash layers in the selected cores have been reworked and therefore are not primary. Because of the induration and silicification of the core samples at quite shallow depths in the core, the other aim of the project (to reconstruct palaeoceanographic changes from 16-0 Ma) was not possible. The spreadsheet contains a full list of samples and a list of samples that have been examined and analysed. The data worksheet contains the no. of Globigerinoides ruber (with weight), Oridorsalis umbonatus, Uvigerina spp. and Cibicidoides spp. specimens for specific samples. For selected samples, stable oxygen and carbon isotopes are given and a graph of the carbon isotopes vs depth in core is presented.
The dataset includes oxygen and carbon stable isotopes measured on multispecies planktonic foraminifera from 15 million years ago to the present, as well as trace elements ratio and abundance counts. For the code availability and instructions to run the cGENIE version and experiments see Boscolo-Galazzo, Crichton et al. (2021).
Groundwater and gas samples collected from sites in the Vale of Pickering and analysed for major gas concentrations, methane stable isotopes, and noble gas compositions.
Nannofossil biostratigraphy, 46x stable bulk carbonate stable isotope measurements (oxygen and carbon) and 71x % organic carbon and % carbonate measurements from between 1313.71 and 1326.82 mbsf at IODP Site U1480.
A selection of abstracts and posters presented at international conferences as part of EPSRC Grant #EP/K036033/1.
Oxygen and carbon isotope ratios (δ18O, δ13C) were measured on 10 to 12 shells of mixed-layer dwelling species Globigerinoides subquadratus from the 250 to 315 μm size fraction from 425 meters composite depth (mcd) until its extinction at 390 mcd. Analyses then continue with Globigerinoides spp. until 350 mcd. In a few samples, where foraminiferal density was low, only 5–7 specimens were analyzed. Analyses were made with a VG Optima mass spectrometer with multi prep device at the British Geological Survey, Keyworth, UK. When picking shells, care was taken to exclude individuals with broken or missing chambers, although preservation of specimens was generally excellent (Fox & Wade, 2013). The external reproducibility of our measurements is ±0.07‰ and ±0.05‰ for δ18O and δ13C respectively. To examine the reproducibility of the results, duplicate measurements were made on 35 samples (5%), which indicate mean reproducibility better than ±0.12‰ and ±0.14‰ for δ18O and δ13C, respectively. Oxygen isotope data are reported as per mil on the VPDB scale (Table S1) calibrated through laboratory and international standards. At ODP Site 1146, δ18O and δ13C were measured by Holbourn et al., (2010) on the mixed-layer dwelling planktonic foraminifera Globigerinoides obliquus or Gs. subquadratus, using 10 to 20 well-preserved tests from the size fraction 250-350 μm. Paired measurements in 51 samples indicate no significant offset in δ18O and δ13C between Gs. obliquus and Gs. subquadratus. Detailed methods are outlined in Holbourn et al., (2010). δ13C data are not used here. For Mg/Ca analyses, we selected 25–35 specimens of Trilobatus quadrilobatus (140–550 μg) from the 250 to 315 μm size fraction; the same size fraction as used for δ18O analysis, to minimize size-related intraspecific elemental variation (Elderfield et al., 2002). Analyses were performed on 86 samples over the studied interval. The tests were gently crushed and subsequently cleaned according to the protocol of Martin & Lea (2002) to remove clays. Cleaning included a reductive step with hydrazine to remove Mn-(hydr)oxides. Samples were measured on an ICP-AES device at Christian-Albrechts-Universität zu Kiel, Germany. Analytical precision is ~1.1%, based on measurements of an internal laboratory standard. Replicate Mg/Ca measurements revealed an average standard deviation of ~0.08 mmol/mol. Adequate cleaning is indicated by very low Fe/Ca, Al/Ca and Mn/Ca ratios.
This dataset contains the low-resolution isotopic data (O & C) covering the last 1Ma, which is used to establish a more precise glacial-interglacial stratigraphy than the shipboard bio/paleomagneto stratigraphy for 2 NW Pacific Sites (IODP EXP350 1436C and 1437B) both were recovered at intermediate depths. The planktonic foraminifera census counts are used to assess the changes in surface water in the area affected by the Kuroshio Current. They are also used in concert with other sedimentological, micropaleontological or taphonomical evidences to estimate the changes in carbonate preservation at intermediate water depth in relation to changes in global ocean circulation during glacial interglacial cycles. Data report: Pleistocene planktonic foraminiferal oxygen and carbon stable isotope records and their use to improve the age model of Hole U1436C ores recovered east of the Aogashima Volcano, Maryline J. Vautravers