Glass major element geochemical data on Late Quaternary tephra deposits from the Main Ethiopian Rift volcanoes. These data were acquired using Electron Microprobe Analysis, and secondary standard data (MPI-DING glasses) are also included. All samples were given a unique name related to the outcrop from which they were obtained. Outcrops are named "MER" followed by a 3-digit number (e.g. MER153). Samples from a given outcrops are given the same name, followed by a letter (e.g. MER153A). Outcrop localities, with GPS coordinates (Lat Long WGS84) and brief description of the geology are also included. These data are published as Supplementary Files to a paper published in Journal of Volcanology and Geothermal Research: Fontijn et al (2018), https://doi.org/10.1016/j.jvolgeores.2018.02.001.

Modal mineralogy data of iceberg-rafted debris deposited at IODP Site U1538 in the Scotia Sea 1.2 million years ago based on QEMSCAN® analyses, which infer minerals from chemistry

Major, trace element and REE analyses of muds and mudstones from selected intervals from all of the holes. Location of the drill holes are given in the Exp. 352 cruise report (Reagan et al)

Radiocarbon measurements on planktic and benthic foraminifera from sediment cores in the North Atlantic: Ocean Drilling Program (ODP) 983, SU90-44, MD04-2829, MD01-2461, and EW9302-2JPC Site 983 is located on the Bjorn Drift in approximately 1650 m water depth on the eastern flank of the Reykjanes Ridge. Hole 983A Position: 60°24.200'N, 23°38.437'W. Sediment core SU90-44 collected from the north-eastern Atlantic basin, near the top of a small abyssal hill, southeast of the Rockall plateau, 50°01'N, 17°06'W, 4279 m. Sediment core MD04-2829 collected from Rosemary Bank in the Northern Rockall Trough 58º 56.93’ N; 09º 34.30’ W; 1743 m water depth. Sediment core MD01-2461 was collected from the north-western flank of the Porcupine Seabight approximately 550 km to the southwest, 51°45’N, 12°55’W; 1153 m water depth, recovered in 2001. Core EW9302-2JPC recovered from the Rockall Plateau and East Flank of Reykjanes Ridge from the Flemish Cap in the south- eastern Labrador Sea, 48°47.70′N, 45°05.09′W, taken at water depth 1251m.

This dataset gathers the data collected during a brine:CO2 flow-through experiments conducted on three sandstones with similar mineralogical compositions (major minerals) but different porosity, clay-size fraction and clay mineralogy. The aim was to study the effect of such heterogeneities on interpretation of geophysical data. Geophysical and transport data were collected before, during and after exposing each sample to CO2, and analysed with basic petrophysical properties. The tests were conducted in the high-pressure, room-temperature (20°C) experimental setup for multi-flow-through tests in the Rock Physics Laboratory at the National Oceanography Centre, Southampton (NOCS), during 2022, as part of the OASIS, EHMPRES and FOCUS projects with funding from the Research Council of Norway (RCN grant no. 280472 - OASIS) and the Natural Environment Research Council (NERC grants NE/X003248/1 - FAPESP-EHMPRES, and NE/X006271/1 - FOCUS). To simulate the specific effective stress conditions of the target CO2 storage reservoir in Aurora (Aker et al., 2021), northern North Sea, the confining and pore pressure conditions of the reservoir were accommodated to our lab temperature conditions. We measured ultrasonic P- and S-wave velocities and attenuations, axial strains and electrical resistivity for an increasing CO2 saturation. The degree of brine saturation was inferred from the electrical resistivity using the modified Archie’s empirical relationship to account for the contribution of clay minerals, based on the Waxman–Smits–Juhasz model (see further details in, e.g., Falcon-Suarez et al. (2021)). We refer to Falcon-Suarez et al. (2020) for further information about the experimental rig and the CO2 injection protocol.

Geochemical measurements which quantify the lithium isotope ratios (d7Li) of Paleozoic (541–251 Mya) mudstones. Samples were obtained from various field locations across Scotland, Wales, England and New Brunswick, Nova Scotia, Canada. Sampled mudstones are listed under their formation name, with information on the locations of each outcrop belt and further details on lithological characteristics, including environment of formation, freely available on the British Geological Survey Lexicon of named rock units (https://www.bgs.ac.uk/technologies/the-bgs-lexicon-of-named-rock-units/) and Government of Canada weblex (https://weblex.canada.ca/weblexnet4/weblex_e.aspx), for UK and Canadian samples, respectively. Stratigraphic age is given in accordance to the GSA geological timescale v.5.0. Following sampling, specific methodologies for preparation for Lithium isotope analysis are provided in the Metadata Lineage. The data was collected to understand changes in weathering intensity coeval with the Paleozoic expansion of land plants, with lithium isotopes a powerful trace for silicate weathering as they are sensitive to the balance between rock dissolution and clay formation. The tabulated lithium isotope ratios were compared at different temporal stages of plant evolution through the Paleozoic. Samples were collected by the University of Cambridge. Lithium isotope ratios were obtained by William McMahon and supervised by Edward Tipper and Mohd Tarique. Mass spectrometry was carried out by William McMahon and David Wilson at University College London.

Data for the figures in the manuscript: S. K. Sahoo, H. Marin-Moreno, L. J. North, I. Falco-Suarez,B. N. Madhusudhan, A. I. Best and T. A. Minshull (2018).Presence and consequences of co-existing methane gas with hydrate under two phase water-hydrate stability conditions , Journal of Geophysical Research: Solid Earth. https://doi.org/10.1029/2018JB015598

The Borzęcin natural gas reservoir has been producing gas since the 1970s. The natural gas reservoir is located in the Zielona Góra basin, in the Polish part of the European Permian Basin. The reservoir is within the Rotligend sandstones and Zechstein carbonates and is capped by the Zechstein evaporites. Gas generation is proposed to be from the Carboniferous organic deposits with later migration into the Permian In May 2019, 2 wells at the Borcezin site were sampled for methane gas analyses. The following analyses were conducted: - Gas composition (C1-C5, CO2, N2, H2S, Ar) and and stable isotope analyses (methane δ13C and δD, CO2 δ13C, δ15N) - Methane clumped isotope analyses (Δ13CD and ΔDD) The dataset was created within SECURe project (Subsurface Evaluation of CCS and Unconventional Risks) - https://www.securegeoenergy.eu/. This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 764531

This study explored the links between host rock composition, hydrothermal fluid composition (particularly pH), and the resulting ore minerals and deposits. The progressive water–rock reaction between 1 kg of initially acidic, condensed magmatic vapour and a series of different rock compositions was modelled with CHILLER (Reed, 1982, Reed, 1998), and follows the design of the water-rock reactions of Reed (1997). The thermodynamic data used in the numerical experiments are from the database SOLTHERM.H08 (Reed and Palandri, 2013). Data and calculations within SOLTHERM include: equilibrium constants calculated with SUPCRT92 (Johnson et al., 1992); mineral thermodynamic data for silicates, oxides, hydroxides, carbonates, gases (Holland and Powell, 1998) and sulphides (Shock, 2007). Mineral solid solutions are represented by end-member compositions that are mixed using an ideal multisite mixing scheme. Rock compositions used in the modelling represent a sub-alkaline andesitic control, and a number of alkaline compositions associated with world-class Au deposits. All starting rock compositions are derived from whole rock geochemical data, and have been recalculated to a 100% basis without TiO2 or P2O5 (excluded as minor phases with little to no effect on hydrothermal mineral assemblages). Original total Fe (as Fe2O3) has been recalculated to FeO and Fe2O3 using the method of Müller et al. (2001). The andesite is representative of calc-alkaline, silica saturated compositions, and is derived from and discussed in detail in Reed (1997). The Luise “Phonolite” (a trachyandesite using the Le Maitre et al., 1989 TAS plot; Fig. 1) and Trachyandesite are from the vicinity of the Ladolam epithermal Au deposit, Lihir Island, Papua New Guinea (Müller et al., 2001). The Porgera Mugearite and Feldspar Porphyry represent unaltered host rock compositions (Richards, 1990) from the Porgera Au deposit (Papua New Guinea). The Cripple Creek Phonolite is part of the host suite to the Cripple Creek epithermal Au deposit, Colorado (Kelley et al., 1998). The Savo trachyte (Smith et al., 2009) represents a typical host rock of the active hydrothermal system (Smith et al., 2010), on Savo island, Solomon Islands. With the exception of the Andesite, all compositions are alkaline using the total alkali versus silica definition of Irvine and Baragar (1971). The Savo sample is not associated with known epithermal Au mineralisation; this composition was selected on the grounds that it represents an evolved (SiO2-rich) silica-saturated, alkaline composition. The initial fluid composition is based on a condensate from Augustine volcano (Symonds et al., 1990) mixed 1:10 with pure water (Reed, 1997; Table 2). A single starting fluid for all models was chosen so as to demonstrate the effect of host rock alone.

This dataset contains 6 tables covering all analytical data for samples collected from the Anyue gas field, central Sichuan Basin, China. Table 1 includes major gas species and stable carbon and hydrogen isotopes. Table 2 includes results for methane clumped isotopes and calculated methane formation temperatures of gas samples. Table 3 includes noble gas concentrations. Table 4 includes noble gas isotopic ratios. Table 5 includes parameters used in methane emission model and calculating total volume of methane emission. Table 6 includes gas composition and stable carbon and hydrogen isotope characteristics of major gases produced in the pyrolysis experiments (thermally equilibrated methane between 400~500 in theory) and working reference gas, and their methane clumped isotope values.