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This spreadsheet contains 21 oxygen isotope measurements for hematite and mixed hematite/goethite samples from the supergene profiles of the Spence and Cerro Colorado porphyry copper deposits in the Central Andes. Columns are also included which contain calculated isotopic values for weathering fluids which were present at the time of iron oxide formation. These data are presented and discussed in the G-cubed paper 'A rusty record of weathering and groundwater movement in the hyperarid Central Andes' (Shaw et al., 2021). Weathering fluid isotopic values are calculated using the published fractionation factors of Clayton & Epstein (1961), Yapp (1990) and Bao & Koch (1999). The authors have the most confidence in the fluid values obtained using the fractionation factor of Yapp (1990), for reasons outlined in the publication.