This dataset contains the results of a laboratory study investigating the dissolution of UO3•nH2O particles in dynamic sediment/groundwater column systems, representative of the shallow subsurface at the Sellafield Ltd. site, UK. Measurements were carried out to determine the extent of uranic particle dissolution and the speciation of dissolved uranium within the columns under contrasting biogeochemical conditions (oxic and electron-donor amended). Columns effluents were analysed periodically for key biogeochemical indicators (nitrate, sulfate) and trace metals (iron, manganese, uranium) and systems were sacrificed after 6 and 12 months of groundwater flow. Upon sacrifice, columns were cross-sectioned, and the sediment structure preserved for synchrotron micro-focus X-ray Fluorescence (XRF) mapping, and uranium L-edge X-ray Absorption Spectroscopy (XAS) measurements. Sub-samples of column sediments were also analysed for acid extractable metals, microbial abundance and classification and bioavailable Fe(II) concentrations. Experiments were performed between March 2016 and March 2017. Subsequent analyses were performed between March 2017 and December 2018. This data was collected as part of the project: Understanding radioactive ‘hot’ particle evolution in the environment funded by the UK Natural Environment Research Council (grant NE/M014088/1). Full details about this nonGeographicDataset can be found at https://doi.org/10.5285/2702e1b0-13df-4ae4-9f91-4ac4bd07bbf1

Data comprise of radionuclide and stable element concentrations in vegetal and animal food and feedstuffs, and their corresponding transfer coefficients and concentration ratios determined in Mediterranean ecosystems in Spain. The considered foodstuff groups are: cereals, grapevine (including wine), olive tree (including olive oil), lamb, beef, pork, and dairy products from sheep, goat and cow. The data include: elemental and radioactive concentration in soil, plants, food and feedstuffs; dry to fresh ratios for foodstuffs; animal feeding diet; estimation of overall elemental and radioactive diet concentration; transfer coefficients for vegetal foodstuffs (relating dry matter elemental and radionuclide concentration in foodstuff to the dry matter concentration in soil); and concentration ratios for animal foodstuffs (relating fresh matter elemental and radionuclide concentration in foodstuff to the dry matter concentration in feedstuff). Radionuclide concentrations presented include Ra-226, Cs-137, Ra-228 and K-40. Elemental concentrations presented include Cs, Sr, K, Na, Ca, Mg, P, Pb, U and Th. Full details about this dataset can be found at https://doi.org/10.5285/48d5395e-e9fb-45ed-b69f-1ea0d2d36be6

Data comprise estimates of activity concentrations of naturally occurring radionuclides (40K, 238U and 232Th series radionuclides) in environmental media (soil and stream sediments and waters) and non-human biota (focusing on the ICRP Reference Animals and Plants). For soil, stream sediments and stream waters data were derived from total K, U and Th concentrations mainly from the ongoing geochemical survey of the United Kingdom (G-BASE), conducted by the British Geological Survey. The geochemical survey data are currently incomplete for England and Wales, but almost complete coverage was obtained for K in stream sediments by using the Wolfson Atlas data for southern England. For U and Th in sediments and K, U and Th in soils, more complete coverage was achieved by geological extrapolation (using relationships between soils/sediments and bedrock/superficial geology). For media and sediments, datasets are provided for both: (i) geometric mean concentrations from measured samples on a 5 x 5 km square basis where data are available; and (ii) extrapolated surfaces covering all of England and Wales. Data for non-human biota are from targeted sampling and analyses and data review. Full details about this dataset can be found at https://doi.org/10.5285/bb2d7874-7bf4-44de-aa43-348bd684a2fe

The data comprise measurements of the 'soluble', 'chemically exchangeable' and 'isotopically exchangeable' U concentrations in a diverse set of soils following experimental addition of UO22+ and incubation in the laboratory under controlled temperature conditions for ca. 1.7 years. The long term behaviour of U in aerobic soils was studied by conducting a laboratory-based experiment in which a set of twenty topsoils from central England with contrasting properties (e.g. pH, organic matter content, land use) were contaminated with a solution containing UO22+ in soluble form and incubated in the dark, in a moist but aerobic condition, at a temperature of 10 deg C for 619 days. The transformations of U in each soil microcosm were periodically monitored by means of soil extractions conducted on subsamples of incubated soils. The resulting dataset enabled quantification of the kinetics of UO22+ transformations in aerobic soils and the relationships with soil properties and land uses (arable, grassland and moorland/woodland). The dataset will be useful in developing models of long-term U bioavailability in aerobic soils under temperate conditions. Full details about this dataset can be found at https://doi.org/10.5285/0d8b2aea-574c-4cff-a8bd-17115a0b90fc

Discrete data for trace elements for both the dissolved and acid available fractions for thirteen core sites in the Humber catchment over the period 1993 to 1997 and for three sites from the Tweed catchment over the period 1994 to 1997. Part of the Land Ocean Interaction Study project (LOIS). Trace elements measured were: Aluminium (Al), Antimony (Sb), Arsenic (As), Barium (Ba), Beryllium (Be), Boron (B), Cadmium (Cd), Cerium (Ce), Chromium (Cr), Cobalt (Co), Copper (Cu), Gadolinium (Gd), Iron (Fe), Lanthanum (La), Lead (Pb), Lithium (Li), Manganese (Mn), Molybdenum (Mo), Neodymium (Nd), Nickel (Ni), Rubidium (Rb), Samarium (Sm), Scandium (Sc), Strontium (Sr), Tin (Sn), Uranium (U), Yttrium (Y), Zinc (Zn). The Core sites were sampled at regular weekly intervals and more intermittently during high flows (on average an extra sampling once a month per site). The Swale sites were sampled during hydrological events and the Aire sites were sampled both weekly and during hydrological events. The majority of samples were obtained using a wide neck grab sampler. Those samples collected from the Aire during hydrological events were obtained using EPIC automatic samplers. Both dissolved and acid available trace element fractions were determined for all samples. The dissolved fraction was measured by filtering samples and acidifying the filtrates with concentrated aristar grade nitric acid (1%vv) on the same day of sampling. The acid available fraction was determined by acidifying an unfiltered sample as above and agitating for 24 hours, at room temperature, prior to filtration. Samples were then analysed by inductively coupled plasma optical emission spectrometry (ICP-OES: B, Ba, Fe, Mn, Sr) and mass spectrometry (ICP-MS: Al, As, Be, Cd, Ce, Co, Cr, Cu, Gd, La, Li, Mo, Nd, Ni, Pb, Rb, Sb, Sc, Sm, Sn, U, Y, Zn). Full details about this dataset can be found at https://doi.org/10.5285/69f62656-567c-42dd-bb65-8f0cbbeb1693