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Metal concentrations in the atmosphere

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    The UK Surface Ocean-Lower Atmosphere Study (UK SOLAS) marine fieldwork data set comprises all data, marine or otherwise, collected during sea-going activities. The fieldwork included eight dedicated research cruises in the eastern North Atlantic Ocean, spanning the period 2006-2008. These cross-disciplinary missions resulted in a diverse data catalogue. This includes meteorology (3-D wind speed and direction, total irradiance, Photosynthetically Active Radiation/PAR, air temperature, atmospheric pressure, humidity, aerosol optical thickness); atmospheric composition (carbon dioxide concentration, aerosol particle counts and size spectra, chemical analyses of aerosol particle composition, cloud condensation nuclei/CCN, concentrations of pollutants such as black carbon, concentrations of free radical species such as iodine monoxide and nitrate radicals); chemical and energy-fluxes across the air-sea boundary (dust deposition rates, oxygen and nitrogen fluxes, carbon dioxide fluxes, sensible heat fluxes, latent heat fluxes, momentum fluxes); biological, chemical and physical properties and processes in the sea surface micro-layer (chlorophyll concentration, bacterial production, phytoplankton and bacterial speciation, concentrations of biogenic trace compounds such as halocarbons, nitrous oxide, dimethyl sulphide/DMS and alcohols, surfactant concentrations, halogen concentrations such as iodine, iodide and iodate); biological, chemical and photochemical properties and processes in the ocean subsurface (primary productivity, trace gas production, plankton community composition, nutrient concentration, concentrations of trace metals such as iron, aluminium, manganese, magnesium and cobalt, ligand and complex metal chemistry parameters such as heme, dust dissolution, salinity, temperature, amino acids and urea, carbonate system chemistry including alkalinity); and sea-state physics (breaking waves, wave slope, whitecaps, bubble size spectra, aerosol formation, subsurface acoustics). Additionally, time series of air-sea fluxes were measured from the Norwegian weather ship, Polarfront, between 2006 and 2009. UK SOLAS scientists also participated in the Bergen Mesocosm experiment during 2008. This simulated gas exchanges and biological, chemical and photochemical properties and processes in the sea surface micro-layer under controlled conditions. The study united atmospheric and marine scientists from institutions across the UK and international collaborators. The UK SOLAS data set was intended to advance understanding of the mutual interactions between the atmosphere and the oceans, especially the chemical exchanges that affect ocean productivity, atmospheric composition and climate. It was funded by the UK Natural Environment Research Council, as the UK's contribution to the international Surface Ocean-Lower Atmosphere Study (SOLAS). The data are held at the British Oceanographic Data Centre (BODC) and have been incorporated into the National Oceanographic Database (NODB). Data collected from non-ship based activities, for example land-based atmospheric data and data resulting from campaigns using the Facility for Airborne Atmospheric Measurements (FAAM) aircraft are held at the British Atmospheric Data Centre (BADC).

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    The dataset comprises hydrographic profiles (temperature, salinity, oxygen, fluorometer, transmissometer, irradiance) and along track measurements (bathymetry, surface meteorology, sea surface hydrography), with discrete measurements including water chemistry (organic and inorganic nutrients, particulate organic carbon and nitrogen, dissolved gases, trace metals), biology (phytoplankton, zooplankton, primary production, community respiration, chlorophyll, pigments) and atmospheric particulates (major ions, organics and trace metals). Data have been collected from meridional transects of the Atlantic Ocean (between the UK and the Falkland Islands, South Africa or South America) from 1995 to the present day. The Atlantic Meridional Transect (AMT) programme aims to study the factors determining the ecological and biogeochemical variability of planktonic ecosystems in the tropical and temperate Atlantic Ocean, and their links to atmospheric processes. The majority of the data are available to academia for re-use and re-purpose but data from recent cruises may be subject to a moratorium which allows first use for data originators. The AMT is coordinated by Andy Rees (AMT Principal Investigator) and Miss Dawn Ashby (AMT Project Officer) at the Plymouth Marine Laboratory (PML) in conjunction with the National Oceanography Centre. Since its inception the programme has involved researchers from several different countries and has acted as a platform for national and international collaboration. Data are managed by the British Oceanographic Data Centre.

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    The dataset comprises hydrographic data, including salinity, temperature, depth, dissolved oxygen, transmittance (for suspended sediment), chlorophyll, irradiance, and current velocities. Both oceanographic and benthic measurements of nutrients (nitrate, nitrite, silicate, phosphate and ammonium), phytoplankton and zooplankton abundance, dissolved and particulate trace metals, primary and bacterial production, sulphur compounds and halocarbons were collected, as well as atmospheric physical and chemical measurements. The data were collected in the North Sea between August 1988 and October 1990 over a series of 38 cruises on RRS Challenger. Oceanographic measurements were taken using hydrographic profilers, moored instruments and shipboard underway systems. Underway meteorological data were also collected in addition to a comprehensive atmospheric sampling programme. Both continuous and discrete water samples were collected, providing biogeochemical and biological data. These were supplemented by net hauls. Benthic processes were investigated with sediment cores taken on eight survey cruises at six sites of varied character, three being in the area of summer stratification. Water and benthic sample analyses were supplemented by results of seabed and shipboard incubation experiments. The North Sea Project evolved from a NERC review of shelf seas research, which identified the need for a concerted multidisciplinary study of circulation, transport and production. The Proudman Oceanographic Laboratory (POL), now the National Oceanography Centre (NOC) hosted the project. It involved over 200 scientists and support staff from the Natural Environment Research Council (NERC), the Ministry of Agriculture, Fisheries and Food (MAFF - now DEFRA) and other academic institutes. The data are held at the British Oceanographic Data Centre and are available on CD-ROM.