Isotope analysis data. Project details: The continental crust is our only archive of Earth history; not just of the crust itself but of the hydrosphere, atmosphere and biosphere, and of the deep Earth through its interactions with the crust. This archive, like the rock record itself, is incomplete and much effort is focused on interrogating the crust to gain a clearer and more complete picture of Earth history. The continental rock record is episodic with, for example, ages of igneous crystallization, metamorphism, continental margins, and seawater and atmospheric proxies distributed about a series of peaks and troughs that in part correspond with the cycle of supercontinent assembly and dispersal. At the core of the debate is what these well-established peaks of ages in the geological record represent and how they develop. The peaks of ages correspond with periods of global assembly of continents to form supercontinents. The project will address whether the peaks of ages are primary features associated with supercontinent assembly or break up, or they are they secondary features representing greater preservation potential at the times of supercontinent assembly. Our work will focus on the Rodinian supercontinent cycle, which extends from initiation of convergent plate interaction around 1.7 Ga, to continental collision at 1.1-1.0 Ga during the Grenville orogeny, to final breakup of the supercontinent by 0.54 Ga. Detrital zircons from sedimentary units throughout the supercontinent cycle provide a record of the magmatic activity for which the igneous rocks are often no longer preserved. We will determine (i) the ages ranges of magmatic activity preserved in the sedimentary rocks in the 600 Ma pre-collision phase, and (ii) how and when the distinctive Grenville peak of ages developed by comparing the zircon record from samples pre-, syn- and post- Rodinian supercontinent assembly with estimated volumes of magma and numbers of zircons produced during the same interval. This will differentiate primary generation processes from secondary processes, constraining when the dominant age peak developed, the tectonic processes that operated, and hence the method by which it developed. The wider implications of when the continental crust formed are considerable. Studies of continental growth continue to uncritically assume that the geological and isotopic record provide insight into processes of crust formation. Until it can be established whether the record is the outcome of generational or preservational processes, or a combination of both, then drawing conclusions on this fundamental question in the Earth Sciences are premature. If the record is a preservational record then this impacts on understanding continental growth through time and on secondary questions of how the crustal record is used to unravel the temporal evolution of the hydrosphere and biosphere, and the distribution of mineral deposits.

The BGS Geochemical Baseline Survey of the Environment (G-BASE) was the national strategic geochemical mapping programme in Great Britain. The project set out to establish the chemistry of the surface environment by the collection and analysis of stream sediment, stream water and soil samples. Beginning in the late 1960s in northern Scotland and moving southwards across the country, the primary focus was mineral exploration, however, the project quickly developed to address important environmental concerns. The final G-BASE samples were collected in southern England in 2014. The outputs from the G-BASE project provide an invaluable, systematic baseline of geochemical information for Great Britain, serving as a marker of the state of the environment against which to measure future change. Sampling Stream sediments were the primary sample medium for G-BASE. The sediment was collected from the centre of the stream and sieved through two sieves (2 mm and 150 µm) to obtain a fine grain-size fraction of <150 µm. Excess material from the <2 mm fraction was panned to collect a heavy mineral concentrate. Stream water samples were collected also at each drainage site. Four different water samples were collected routinely: two filtered waters (for major and trace elements) and two unfiltered waters (for pH, conductivity and alkalinity). The routine collection of soil samples was introduced in 1986 in areas of poor drainage density, and urban soil sampling commenced in 1991. Further details of the sampling methodology can be found in the G-BASE field procedures manual (https://nora.nerc.ac.uk/id/eprint/5190/). Sample analysis Stream water pH, conductivity and alkalinity were determined in the field. Water samples were returned to our laboratories and analysed by inductively coupled atomic emission and mass spectrometry (ICP-AES/MS), ion chromatography (IC) / ion selective electrode (ISE) for up to 50 chemical parameters. Waters were also analysed for non-purgeable organic carbon (NPOC) to determine dissolved organic carbon content. Most water samples were analysed for alkalinity, pH, conductivity, F and U and some for multi-element analyses including Al, Cl, Na, Si, SO4, NO4, and TOC. The <150 µm fraction of the stream sediment and the <2 mm fraction of topsoil were analysed by techniques including X-ray fluorescence (XRF) / direct reading optical emission spectrometry (DR-OES) to determine the concentration of up to 53 major and trace elements. Loss on ignition (LOI) and pH were determined in topsoil samples. Analytical data for the 150 micron fraction of soil and stream sediment samples are available for some or all of: Ag, As, B, Ba, Bi, Be, Ca, Ce, Cd, Co, Cr, Cs, Cu, Fe, Ga, K, La, Li, Mg, Mn, Mo, Nb, Ni, P, Pb, Rb, Sb, Se, Sn, Sr, Th, Ti, U, V, Y, Zn, Zr. In later stages, the project also routinely determined the elements listed in the <2 mm fraction of surface soils. Sample storage and archive After preparation and analyses all soil, stream sediment and panned concentrate samples and excess material were stored and archived at the National Geoscience Data Centre (NGDC). The archive holds more than 40 years’ worth of material collected across the UK. Archived samples can be made available for further tests and analyses on request by contacting BGS Enquiries (mailto:enquiries@bgs.ac.uk).

This dataset relates to sample metadata and the results of geochemical analyses conducted on samples as part of the Mineral Reconnaissance Programme (MRP). It contains metadata including sample names, sample project areas, sample types and analytes. The MRP was a programme undertaken by BGS which ran continuously from 1973 to 1997, funded by the UK Government's Department of Trade and Industry (DTI). The datasets it produced provide baseline information on areas prospective for the occurrence of metallic minerals in particular locations across Great Britain. The programme was designed to stimulate private sector exploration and to encourage the development of Britain's indigenous mineral resources. The emphasis during the MRP varied in response to market conditions and strategic interests. Work on ‘strategic’ metals, such as platinum, palladium, chromium, cobalt and nickel, dominated the 1980s. From the late 1980s, the principal focus of the programme was gold. Numerous studies examined gold mineralisation in porphyry, epithermal, orogenic and unconformity-related settings. Towards the end of the programme, a small number of projects concerned with gemstones and industrial minerals were also completed. Various samples were taken throughout the course of the programme, including rock, soil, stream sediment, stream water and deep overburden samples. These samples underwent analysis for a variety of analytes, the results of which are held by BGS. This dataset includes the geochemical information derived from the samples and sample metadata, including the location of sampling. The sampling and analysis methodology varied by MRP project area. For more information about the samples from a specific project area, refer to the MRP report for that project: https://nora.nerc.ac.uk/cgi/search/archive/advanced?screen=Search&dataset=archive&_action_search=Search&series=Mineral+Reconnaissance+Programme For more information about obtaining the results of sample analyses, contact BGS Enquiries (enquiries@bgs.ac.uk). For more information about the MRP, see the MineralsUK website: https://www.bgs.ac.uk/mineralsuk/exploration-and-maps/mrp-reports/.

The BGS Geochemical Baseline Survey of the Environment (G-BASE) was the national strategic geochemical mapping programme in Great Britain. The project set out to establish the chemistry of the surface environment by the collection and analysis of stream sediment, stream water and soil samples. Beginning in the late 1960s in northern Scotland and moving southwards across the country, the primary focus was mineral exploration, however, the project quickly developed to address important environmental concerns. The final G-BASE samples were collected in southern England in 2014. The outputs from the G-BASE project provide an invaluable, systematic baseline of geochemical information for Great Britain, serving as a marker of the state of the environment against which to measure future change. The routine collection of regional soil samples was introduced in 1986 in areas of poor drainage density, with an average sample density of one site per 2 square kilometres. Urban soil sampling commenced in 1991, with an average density of four samples per square kilometres, for the urban areas of Belfast, Cardiff, Corby, Coventry, Derby, Doncaster, Glasgow, Hull, Ipswich, Leicester, Lincoln, Manchester, Mansfield, Northampton, Nottingham, Peterborough, Scunthorpe, Sheffield, Swansea, Stoke, Telford, Wolverhampton and York. Topsoil samples were collected between depths of 5 cm and 20 cm, and were sieved through a 2 mm mesh and milled to less than 150 microns. The data include XRF and direct-reading optical emission spectrometry (DR-OES) analyses for some or all of the following elements: Ag, As, Ba, Bi, Br, Ca, Cd, Ce, Co, Cr, Cs, Cu, Fe, Ga, Ge, Hf, I, K, La, Mg, Mn, Mo, Nb, Ni, P, Pb, Rb, Sb, Sc, Se, Se, Sn, Sr, Ta, Te, Th, Ti, Tl, U, V, W, Y, Zn and Zr. Loss on Ignition (LOI) and pH (in a slurry of 0.01 M CaCl2) were also routinely determined on 50% of regional and all urban samples. For more information about accessing these samples and their analytical results, contact BGS Enquiries (enquries@bgs.ac.uk).

The BGS Geochemical Baseline Survey of the Environment (G-BASE) was the national strategic geochemical mapping programme in Great Britain. The project set out to establish the chemistry of the surface environment by the collection and analysis of stream sediment, stream water and soil samples. Beginning in the late 1960s in northern Scotland and moving southwards across the country, the primary focus was mineral exploration, however, the project quickly developed to address important environmental concerns. The final G-BASE samples were collected in southern England in 2014. The outputs from the G-BASE project provide an invaluable, systematic baseline of geochemical information for Great Britain, serving as a marker of the state of the environment against which to measure future change. Deep soil samples (also known as profile soil samples) were taken from depths of between 35 cm and 50 cm at densities of 1 sample per two square kilometres (rural / regional areas) and 4 samples per square kilometre (urban areas). The G-BASE profile soils were generally sieved to 150 microns before analysis and determined by XRF for some or all of: Ag, As, Ba, Bi, Br, Ca, Cd, Ce, Co, Cr, Cs, Cu, Fe, Ga, Ge, Hf, I, K, La, Mg, Mn, Mo, Nb, Ni, P, Pb, Rb, Sb, Sc, Se, Se, Sn, Sr, Ta, Te, Th, Ti, Tl, U, V, W, Y, Zn and Zr. Since 2003, for both regional and urban sampling, deep soil samples and shallow soil samples were routinely collected from the same sites, but only the shallow soil samples were submitted for chemical analysis. The deep soil samples were archived in the National Geoscience Data Centre. For more information about accessing these samples and their analytical results, contact BGS Enquiries (enquries@bgs.ac.uk).

The BGS Geochemical Baseline Survey of the Environment (G-BASE) was the national strategic geochemical mapping programme in Great Britain. The project set out to establish the chemistry of the surface environment by the collection and analysis of stream sediment, stream water and soil samples. Beginning in the late 1960s in northern Scotland and moving southwards across the country, the primary focus was mineral exploration, however, the project quickly developed to address important environmental concerns. The final G-BASE samples were collected in southern England in 2014. The outputs from the G-BASE project provide an invaluable, systematic baseline of geochemical information for Great Britain, serving as a marker of the state of the environment against which to measure future change. Stream water samples were collected at each drainage site. Four different water samples were collected routinely: two filtered waters (for major and trace elements) and two unfiltered waters (for pH, conductivity and alkalinity). Samples were collected for approximately 85% of Great Britain, but a wide range of analytes were only determined from the Wales and Humber-Trent atlas areas southwards. Stream water pH, conductivity and alkalinity were determined in the field. In the later stages of the programme, stream water samples from high order streams were analysed by ICP-AES/MS for 27 elements (Al, B, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, K, La, Li, Mg, Mn, Mo, Na, Ni, P, Pb, S (as SO42-), Si, Sr, V, Y, Zn and Zr) and by quadrupole ICP-MS for 24 trace elements (Ag, Al, As, Ba, Be, Cd, Ce, Co, Cr, Cu, La, Li, Mo, Ni, Pb, Rb, Sb, Sn, Th, Tl, U, V, Y and Zr). Some samples were analysed by ion chromatography (IC). Automated colorimetric methods were used to determine Cl and NO3-, and an ion selective electrode (ISE) technique was used to determine F. Waters were also analysed for non-purgeable organic carbon (NPOC) to determine dissolved organic carbon content. All samples were routinely analysed for pH, conductivity and bicarbonate. Much of the UK coverage also includes uranium and fluoride analyses. For more information about accessing these samples and their analytical results, contact BGS Enquiries (enquries@bgs.ac.uk).

The BGS Geochemical Baseline Survey of the Environment (G-BASE) was the national strategic geochemical mapping programme in Great Britain. The project set out to establish the chemistry of the surface environment by the collection and analysis of stream sediment, stream water and soil samples. Beginning in the late 1960s in northern Scotland and moving southwards across the country, the primary focus was mineral exploration, however, the project quickly developed to address important environmental concerns. The final G-BASE samples were collected in southern England in 2014. The outputs from the G-BASE project provide an invaluable, systematic baseline of geochemical information for Great Britain, serving as a marker of the state of the environment against which to measure future change. At G-BASE drainage sampling sites (average density: one site per 1.5 km square), sediment was collected from the centre of the stream and sieved through two sieves (2 mm and 150 microns). The fine-grained fraction formed the stream sediment sample and underwent chemical analysis. Excess material from the <2 mm fraction was panned using a wooden dulang pan to collect a heavy mineral concentrate. During the G-BASE project, these samples were archived, but not routinely submitted for chemical analysis. For more information about accessing these samples and their analytical results, contact BGS Enquiries (enquries@bgs.ac.uk).

The BGS Geochemical Baseline Survey of the Environment (G-BASE) was the national strategic geochemical mapping programme in Great Britain. The project set out to establish the chemistry of the surface environment by the collection and analysis of stream sediment, stream water and soil samples. Beginning in the late 1960s in northern Scotland and moving southwards across the country, the primary focus was mineral exploration, however, the project quickly developed to address important environmental concerns. The final G-BASE samples were collected in southern England in 2014. The outputs from the G-BASE project provide an invaluable, systematic baseline of geochemical information for Great Britain, serving as a marker of the state of the environment against which to measure future change. Stream sediments were the primary sample medium for G-BASE, with an average density of one site per 1.5 km square. The drainage sampling sites cover most of Great Britain. Sediment was collected from the centre of the stream and sieved through two sieves (2 mm and 150 µm) to obtain a fine grain-size fraction of <150 microns. Analytical data (by a variety of analytical methods, including XRF and direct-reading optical emission spectrometry (DR-OES) for the <150 micron fraction of stream sediment samples are available for some or all of the following elements: Ag, As, Ba, Bi, Br, Ca, Cd, Ce, Co, Cr, Cs, Cu, Fe, Ga, Ge, Hf, I, K, La, Mg, Mn, Mo, Nb, Ni, P, Pb, Rb, Sb, Sc, Se, Se, Sn, Sr, Ta, Te, Th, Ti, Tl, U, V, W, Y, Zn and Zr. Some stream sediment samples were originally collected as part of the Mineral Reconnaissance Programme (MRP), and later re-analysed for G-BASE. These samples may have been assigned a new sample number, but will plot at the same site. For more information about accessing these samples and their analytical results, contact BGS Enquiries (enquries@bgs.ac.uk).

UKGEOS and Core Sample Analysis. Geomechanical testing was performed to determine triaxial compressional strength, tensile strength, frictional strength and permeability of sandstones, siltstones, mudstones and coals from eleven depth intervals within the GGC01 borehole, UK Geoenergy Observatories (UKGEOS), Glasgow, United Kingdom. Frictional strength tests were also performed on cuttings samples of sandstones, siltstones, mudstones and coals from the GGA08 borehole, Glasgow, United Kingdom. In total twenty-three tensile strength tests were performed on ten sampled intervals, and seven porosity measurements pre-and post-failure were taken. Nine triaxial compressive strength tests and twenty-one frictional strength tests were performed, with permeability measured both before and after failure or shear respectively. From compressive strength tests we also determined the Young’s modulus and Poisson’s ratio. Results of X-Ray Diffraction are also included in the dataset.

This Web service provides layers which show metadata relating to geochemical samples held by the British Geological Survey (BGS). The layers are point layers which indicate the spatial locations samples were taken from. Geochemical samples have been collected, analysed and stored in the BGS Geochemistry Database from different projects. The two most significant contributors to the database are the Geochemical Baseline Survey of the Environment (G-BASE) project and the Mineral Reconnaissance Programme (MRP). Each project took a variety of different sample types, including stream water, stream sediment, shallow soil and deep soil, and one layer is provided for each type of sample. The sample metadata provided include: sample name; sample type; the Regional Geochemical Atlas area (for G-BASE samples only) and a comma-separated list of available analytes. In many cases, samples are retained in the National Geoscience Data Centre (NGDC) at BGS Keyworth. For more information about obtaining samples or the results of their geochemical analyses, contact BGS Enquiries (enquiries@bgs.ac.uk).