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  • Final Report for UKCCSRC Call 2 Project C2-189. Novel Reductive Rejuvenation approaches for degraded amine solvents from PCC in power plants.

  • UKCCSRC Call 2 Project C2-189. The data, which was produced as a result of a UK CCSRC Call 2 funded project, consists of the GC-MS characterisation results for the products collected from the rejuvenation tests of degraded amine sorbents from carbon capture and related model degradation compounds. The examined amine-based sorbent samples included one heavily degraded industrial MEA solvent, one degraded solid-supported polyethyleneimine sample and 6 model MEA degradation compounds (N-(2-Hydroxyethyl)-ethylenediamine, glycylglycine, 2-Oxazolidinone, 1-(2-Hydroxyethyl)-2-imidazolidinone, 1-(2-Hydroxyethyl)-imidazole, N-Acetylethanolamine. Novel reductive approaches, which were investigated as a potential means for rejuvenating the degraded amine sorbents and where the samples for characterisation were produced, included catalytic hydrogenation, hydrous pyrolysis and hydropyrolysis with platinum, nickel and molybdenum as the catalysts used. The dataset also contains some preliminary CO2 absorption test results for a degraded MEA solvent before and after rejuvenation with hydrous pyrolysis using a continuous reactor. Full technical details of the research are contained in the final report submitted to UK CCSRC.