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This file documents the strontium isotope data, and the manner in which it has been processed, to supply the reference data for isotope domains of the Biosphere Isotope Domains GB (V1) map. It includes a summary of the analytical methods used to determine the isotope ratios though time.
A worldwide compilation of 14,261 analyses of Nd, Sm, Rb and Sr concentrations, and Nd and Sr isotopes, in crustal rocks with a range of crystallisation ages. These data were used in Dhuime et al. (2015, Nature Geoscience 8, 552-555) to calculate the variation in the 'time integrated' Rb/Sr ratios of the new (i.e. juvenile) continental crust as a function of its Nd model age of formation.
A GEOROC (http://georoc.mpch-mainz.gwdg.de/georoc/) compilation of 8,531 analyses of SiO2, Rb and Sr concentrations, in crustal rocks sampled in central and southwestern America, at sites of various crustal thickness. These data were used in Dhuime et al. (2015, Nature Geoscience 8, 552-555) to establish a positive correlation between Rb/Sr (or SiO2) and crustal thickness in sites of generation of new continental crust. GEOROC - Geochemistry of Rocks of the Oceans and Continents
Elemental and stable isotope data measured in Eocene foraminiferal calcite from Ocean Drilling Program Site 865 and Tanzanian Drilling Project Site 18 published in Edgar et al. (2015) "Assessing the impact of diagenesis on δ11B, δ13C, δ18O, Sr/Ca and B/Ca values in fossil planktic foraminiferal calcite" in Geochimica et Cosmochimica Acta, v. 166, p. 189-209. Table 1. δ18O and δ13C values for glassy and frosty foraminifera from TDP Site 18 and ODP Site 865, respectively. Table 2. Sr/Ca and B/Ca values, and test weights for glassy and frosty foraminifera from TDP Site 18 and ODP Site 865, respectively. Table 3. δ11B values for glassy and frosty foraminifera from TDP Site 18 and ODP Site 865, respectively.
Porewaters from IODP Expedition 366 were extracted from serpentinite mud volcano sediments onboard the RV JOIDES Resolution (see Fryer et al, 2017; 2018 for details). Selected samples were then analysed at the University of Southampton for 87Sr/86Sr and boron isotopes and SUERC for stable hydrogen and oxygen isotope data. The strontium isotope data has recently been accepted for publication (Albers et al., 2019 (In Press) Fluid–rock interactions in the shallow Mariana forearc: carbon cycling and redox conditions, Solid Earth special issue "Exploring new frontiers in fluids processes in subduction zones").
Discrete data for trace elements for both the dissolved and acid available fractions for thirteen core sites in the Humber catchment over the period 1993 to 1997 and for three sites from the Tweed catchment over the period 1994 to 1997. Part of the Land Ocean Interaction Study project (LOIS). Trace elements measured were: Aluminium (Al), Antimony (Sb), Arsenic (As), Barium (Ba), Beryllium (Be), Boron (B), Cadmium (Cd), Cerium (Ce), Chromium (Cr), Cobalt (Co), Copper (Cu), Gadolinium (Gd), Iron (Fe), Lanthanum (La), Lead (Pb), Lithium (Li), Manganese (Mn), Molybdenum (Mo), Neodymium (Nd), Nickel (Ni), Rubidium (Rb), Samarium (Sm), Scandium (Sc), Strontium (Sr), Tin (Sn), Uranium (U), Yttrium (Y), Zinc (Zn). The Core sites were sampled at regular weekly intervals and more intermittently during high flows (on average an extra sampling once a month per site). The Swale sites were sampled during hydrological events and the Aire sites were sampled both weekly and during hydrological events. The majority of samples were obtained using a wide neck grab sampler. Those samples collected from the Aire during hydrological events were obtained using EPIC automatic samplers. Both dissolved and acid available trace element fractions were determined for all samples. The dissolved fraction was measured by filtering samples and acidifying the filtrates with concentrated aristar grade nitric acid (1%vv) on the same day of sampling. The acid available fraction was determined by acidifying an unfiltered sample as above and agitating for 24 hours, at room temperature, prior to filtration. Samples were then analysed by inductively coupled plasma optical emission spectrometry (ICP-OES: B, Ba, Fe, Mn, Sr) and mass spectrometry (ICP-MS: Al, As, Be, Cd, Ce, Co, Cr, Cu, Gd, La, Li, Mo, Nd, Ni, Pb, Rb, Sb, Sc, Sm, Sn, U, Y, Zn). Full details about this dataset can be found at https://doi.org/10.5285/69f62656-567c-42dd-bb65-8f0cbbeb1693
Trace metal mobilisation data (pH, ALK, Na, K, Ca, Mg, Li, SO4, Si, Be, Mn, Fe, Zn, Cu, Al,Sr, Be, Ba, Y,Co, Ni, B, Rb, Y, Cd, Sb, Cs, Ba, La, Ce, Nd, Pb, Th, U) for the River Carnon, the River Fal (downstream) and its estuary in Cornwall following discharge of highly polluted water from the Wheal Jane mine. In January 1992, there was a major pollution incident involving highly acidic wastes. CEH, in conjunction with the University of Reading monitored the River Carnon between September 1992 and April 1994, to examine the water quality.