Measurements of nitrogen and carbon abundances and isotopic ratios for deep-marine ferromanganese crusts and nodules from the modern ocean. This reservoir has not previously investigated as an archive of nitrogen isotopes. The results reveal unusually negative values, interpreted as evidence of partial ammonium oxidation succeeded by adsorption of nitrogen oxides to the mineral surface. More details can be found in Stüeken , E E & Bau , M 2023 , Geochemical Perspectives Letters , vol. 25 , pp. 13-17 . https://doi.org/10.7185/geochemlet.2308 Geographical extent: Central Pacific seafloor, between Kiribati and Wallis and Futuna (0° – 10° S and 175° E – 175° W)

Demonstration of hydrothermal ammonium mobilization in the Paleoproterozoic with possible implications for biological productivity. The data include organic carbon and nitrogen abundances and isotopic ratios, as well as metal abundances. Samples span from sedimentary rocks to altered igneous rocks, where lithologies are provided in the CN data file. The N-enrichment in the usually N-poor igneous rocks indicates transfer of ammonium from organic-rich sediments and can be used to estimate the ammonium concentration of the hydrothermal fluid at the time of deposition. More details are provided in Stüeken, E.E., Kirsimäe, K., Lepland, A. and Prave, A.R., 2023, Astrobiology, 23(2), pp. 195-212.

Organic carbon and bulk nitrogen isotope data for black shale samples from six different drill cores with varying distance from the major Zn ore body (HYC) in the McArthur basin. Data show trends with distance in d15N and C/N ratios. A more detailed interpretation is provided in Stüeken, E.E., Gregory, D.D., Mukherjee, I. and McGoldrick, P., 2021. Sedimentary exhalative venting of bioavailable nitrogen into the early ocean. Earth and Planetary Science Letters, 565, p.116963.

Organic carbon and bulk nitrogen isotope and abundance data and metal abundance data from the Mesoarchean VMS deposit and associated strata. Detailed information is given in Stueeken, E.E., Boocock, T.J., Robinson, A., Mikhail, S. and Johnson, B.W., 2021. Hydrothermal recycling of sedimentary ammonium into oceanic crust and the Archean ocean at 3.24 Ga. Geology, 49(7), pp.822-826.

Organic carbon, bulk nitrogen isotope and bulk sulfur isotope and abundance data and metal abundance data from metapelites of the 3.7Ga Isua Supracrustal Belt. For more details, see Stüeken, E.E., Boocock, T., Szilas, K., Mikhail, S. and Gardiner, N.J., 2021. Reconstructing nitrogen sources to Earth’s earliest biosphere at 3.7 Ga. Frontiers in Earth Science, 9, p.675726.

Organic carbon, total nitrogen, total reduced sulfur and carbonate-associated sulfur isotopes measured on decarbonated stromatolite samples from the Paranoa Group (1.1 Ga).

The dataset includes organic carbon and nitrogen isotope data, as well as elemental abundance data from marine sediments that were obtained by push corers from hydrothermal seeps in the modern Guaymas Basin, Gulf of Mexico. Also included are pore water measurements of ammonium concentrations and nitrogen isotopes of dissolved ammonium, as well as sediment temperatures.

Stable isotope data of organic carbon, nitrogen and sulfur as well as trace elements are used to explore how proxies with differing residence times in seawater respond to changes in the basin’s connectivity to the open ocean. The results show that species with a short residence time, such as nitrate and rare earth elements, may be more sensitive to geologically brief fluctuations in oceanographic conditions than long-lived species like sulfate. Details about the methodology and sampling strategy can be found in Stu¨eken, E.E., Viehmann, S. and Hohl, S.V., 2023, ACS Earth and Space Chemistry, 7(7), pp.1337-1349.

Nitrogen isotopic composition of microbial biomass grown in the laboratory under N2-fixing conditions. Also included are meta-data that describe the experimental conditions. The conditions were chosen to mimic specific parameters of the early Earth, in particular variable CO2 and O2 supplies, to test if d15N data recorded in ancient biomass in the rock record is affected. Also included are data from the wider literature for comparison, as well as the results of statistical tests.

Organic carbon and nitrogen and bulk nitrogen isotope data and metal abundance data for siltstones and shales of the Mesoproterozoic Diabaig Formation. For a detailed description and interpretation, see Stüeken, E.E. and Prave, A.R., 2022. Diagenetic nutrient supplies to the Proterozoic biosphere archived in divergent nitrogen isotopic ratios between kerogen and silicate minerals. Geobiology.