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                                 </gmd:date>
                                 <gmd:dateType>
                                    <gmd:CI_DateTypeCode codeList="https://schemas.isotc211.org/schemas/19139/resources/codelist/gmxCodelists.xml#CI_DateTypeCode"
                                                         codeListValue="publication">publication</gmd:CI_DateTypeCode>
                                 </gmd:dateType>
                              </gmd:CI_Date>
                           </gmd:date>
                        </gmd:CI_Citation>
                     </gmd:specification>
                     <gmd:explanation>
                        <gco:CharacterString>See http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2010:323:0011:0102:EN:PDF</gco:CharacterString>
                     </gmd:explanation>
                     <gmd:pass>
                        <gco:Boolean>false</gco:Boolean>
                     </gmd:pass>
                  </gmd:DQ_ConformanceResult>
               </gmd:result>
            </gmd:DQ_DomainConsistency>
         </gmd:report>
         <gmd:lineage>
            <gmd:LI_Lineage>
               <gmd:statement>
                  <gco:CharacterString>Samples for noble gas and CH4 clumped isotope analysis were collected using 10 mm diameter internally polished refrigeration grade copper tubes sealed with stainless steel pinch-off clamps on both ends. Additional samples for the analysis of gas composition, carbon and hydrogen isotopes were collected using stainless steel cylinders. Bulk gas content as a percentage was determined using an Agilent 6890N gas chromatograph-mass spectrometer (GC-MS). Carbon and hydrogen isotope values were measured using GC-IRMS of Agilent 6890N-Isoprime 100 and Thermofisher 1310-Delta V, respectively. Methane clumped isotopologues were measured by a tunable infrared laser direct absorption spectroscopy (TILDAS, Aerodyne). Noble gas abundance and isotopic ratios were determined by an Isotopx NGX noble gas mass spectrometer.</gco:CharacterString>
               </gmd:statement>
            </gmd:LI_Lineage>
         </gmd:lineage>
      </gmd:DQ_DataQuality>
  </gmd:dataQualityInfo>
</gmd:MD_Metadata>