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Rothera Time Series: Carbonate Chemistry 2010-2020

Seawater samples between 2010-12-28 and 2020-02-28 were collected year-round and quasi-weekly in Ryder Bay, along the West Antarctic Peninsula, as part of the Rothera Oceanographic Time Series (RaTS). The majority of samples were collected at 15 m depth. At a lower frequency, samples were collected at additional depths, i.e., mostly at 40 m, 5, m, and 2 m. Samples have been analysed for dissolved inorganic carbon (DIC) and total alkalinity (TA) to study the carbonate chemistry of the upper ocean, from which the fugacity of CO2 (fCO2) is derived. This dataset also includes additional variables of the RaTS-array that are ancillary to DIC and TA results, and to fCO2 calculations: seawater temperature, salinity, and nutrients (nitrate, silicate, and phosphate). DIC/TA data between 2010-12-28 and 2014-02-21 have previously been published in NCEI by Bakker et al. (2017), and are included in this dataset. Physical variables and nutrient data have also been published in the UK Polar Data Centre by Clarke et al. (2022).

Funding Sources:

Funding sources for Rothera Time Series 2014-2020:

- The Rothera Time Series has been funded by NERC through a sequence of National Capability awards, most recently PRESCIENT (NE/Y006178/1).

- ESD: NE/L002582/1 and European Union''s Horizon 2020 research and innovation programme under grant agreement no. 821001

- DCEB: partly supported by the NERC PICCOLO award (NE/PO21395/1).

- EJ: research programme 866.13.006 (partly) financed by the Netherlands Polar Programme at NWO.

- MPM: partly funded by BIOPOLE award (NE/W004933/1).

Funding sources for Rothera Time Series 2010-2014:

- British Antarctic Survey (BAS) Polar Oceans funding from NERC

- UK Ocean Acidification Research Programme (NE/H017046/1) funded by NERC, the Department for Energy and Climate Change and the Department for Environment, Food and Rural Affairs

- OJL: PhD funding from NERC: NE/L50158X/1

- DCEB: NERC Shelf Sea Biogeochemistry Blue Carbon work package (NE/K00168X/1)

Simple

Alternate title
Polar Data Centre (PDC) record GB/NERC/BAS/PDC/02050
Date (Publication)
2025-05-02
Identifier
http://www.antarctica.ac.uk/dms/metadata.php?id= / GB/NERC/BAS/PDC/02050
Custodian
  British Antarctic Survey
High Cross, Madingley Road , Cambridge , CB3 0ET , UK
+44 (0)1223 221400
Originator
  NERC EDS UK Polar Data Centre - Droste, E., Bakker, D., Venables, H., Jones, E., Legge, O., Hendry, K., & Woodward, E.
High Cross, Madingley , Cambridge , CB3 0ET , UK
+44 (0)1223 221400
Maintenance and update frequency
unknown Unknown
Keywords
  • NDGO0001
NERC OAI Harvesting
  • NERC_DDC
GCMD Parameter Valids
  • EARTH SCIENCE > Oceans > Ocean Chemistry > Alkalinity
  • EARTH SCIENCE > Oceans > Ocean Chemistry > Carbon
  • EARTH SCIENCE > Oceans > Ocean Chemistry > Carbon Dioxide
  • EARTH SCIENCE > Oceans > Ocean Chemistry > Inorganic Carbon
BAS Free-text keywords
  • DIC
  • Dissolved inorganic carbon
  • Rothera
  • Rothera Time Series
  • Ryder Bay
  • TA
  • West Antarctic Peninsula
  • fCO2
  • total alkalinity
Use limitation
Data supplied under Open Government Licence v3.0 http://www.nationalarchives.gov.uk/doc/open-government-licence/version/3/.
Access constraints
otherRestrictions Other restrictions
Other constraints
Data supplied under Open Government Licence v3.0 http://www.nationalarchives.gov.uk/doc/open-government-licence/version/3/.
Metadata language
EnglishEnglish
Topic category
  • Oceans
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Begin date
2010-12-28
End date
2020-02-28
Reference system identifier
OGP / urn:ogc:def:crs:EPSG::4326
Distribution format
Distributor
  Polar Data Centre - British Antarctic Survey
+44 (0)1223 221400
OnLine resource
GET DATA ( http )
Hierarchy level
dataset Dataset

Domain consistency

Measure identification
INSPIRE / Conformity_001

Conformance result

Date
Explanation
See the referenced specification
Pass
No
Statement

Analytical precision of DIC and TA content is determined from CRMs runs on the VINDTA. On each analysis day, sample runs are bracketed by a repeat run on a CRM bottle at the start and at the end. Results of these runs were used to quality check the instrument, and to determine the analytical uncertainty of the measurements by calculating the 1-sigma of all CRM run results per CRM batch. The certified values of the CRMs were used to calibrate the coulometer counts and potentiometric titration and determine DIC and TA content, respectively.

Results for CRMs were excluded when the analytical instrument clearly did not perform well (usually observed in the lab), or when their reproducibility was poor. Results for seawater samples were excluded if the instrument performed poorly, or when the sample had been compromised due to contamination during sampling and/or storage (e.g., if the sample was not gas-tight).

Analytical uncertainties for DIC and TA are less than 2.7 micromol kg-1, with the exception of data between 2016-2017, which had higher uncertainties of less than 5.4 micromol kg-1.

Quality flags in the dataset are indicated by the ''''_FLAG''''-extension in the column name and follow the WOCE quality codes.

File identifier
GB_NERC_BAS_PDC_02050 XML
Metadata language
EnglishEnglish
Hierarchy level
dataset Dataset
Date stamp
2025-05-02
Metadata standard name
NERC profile of ISO19115:2003
Metadata standard version
1.0
Point of contact
  British Antarctic Survey
+44 (0)1223 221400
Dataset URI
http://www.antarctica.ac.uk/dms/metadata.php?id=GB/NERC/BAS/PDC/02050
 
 

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