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Atmospheric nitrous acid amount fraction at Halley in January and February 2022

Atmospheric nitrous acid (HONO) amount fraction measured in the clean air sector at Halley VI Research Station between 22 January and 3 February 2022. The data was collected using a Long Path Absorption Photometer (LOPAP), the instrument inlet height above the snow was changed during the measurement period, this is indicated in the dataset. Temperature and wind speed data were collected are included to enable the HONO flux from the snow to be calculated.

This work was supported by the Natural Environment Research Council and the ARIES Doctoral Training Partnership [grant number NE/S007334/1]. The fieldwork at Halley VI Research Station was funded by the Collaborative Antarctic Science Scheme (CASS).

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Date (Creation)
2023-03-10
Date (Revision)
2023-03-10
Date (Publication)
2023-03-10
Date (released)
2023-03-10
Edition
1.0
Unique resource identifier
https://doi.org/10.5285/94b2f348-d6cc-4bcd-b921-5c0928ab3c2d
Codespace
doi
Unique resource identifier
GB/NERC/BAS/PDC/01718
Codespace
https://data.bas.ac.uk/
Unique resource identifier
NE/S007334/1
Codespace
award
Other citation details
Please cite this item as: Bond, A., Squires, F., Frey, M., & Kaiser, J. (2023). Atmospheric nitrous acid amount fraction at Halley in January and February 2022 (Version 1.0) [Data set]. NERC EDS UK Polar Data Centre. https://doi.org/10.5285/94b2f348-d6cc-4bcd-b921-5c0928ab3c2d
Credit
No credit.
Status
completed Completed
Author
  British Antarctic Survey - Bond, Amelia ( Researcher )
Author
  British Antarctic Survey - Squires, Freya ( Researcher )
Author
  British Antarctic Survey - Frey, Markus ( Researcher )
Author
  University of East Anglia - Kaiser, Jan ( Researcher )
Point of contact
  NERC EDS UK Polar Data Centre
British Antarctic Survey, High Cross, Madingley Road , Cambridge , Cambridgeshire , CB3 0ET , United Kingdom
+44 (0)1223 221400
https://www.bas.ac.uk/team/business-teams/information-services/uk-polar-data-centre/
Maintenance and update frequency
asNeeded As needed
Maintenance note
completed Completed
Global Change Master Directory (GCMD) Science Keywords
  • EARTH SCIENCE > Atmosphere > Atmospheric Chemistry > Trace Gases/Trace Species
  • EARTH SCIENCE > Atmosphere > Atmospheric Chemistry
  • EARTH SCIENCE > Atmosphere > Atmospheric Chemistry/Nitrogen Compounds
Theme
  • atmospheric chemistry
  • nitrous acid
  • reactive nitrogen
  • trace gas
Place
  • Halley VI Research Station Antarctica
GEMET - INSPIRE themes, version 1.0
  • Atmospheric conditions
Access constraints
otherRestrictions Other restrictions
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no limitations to public access
Access constraints
otherRestrictions Other restrictions
Other constraints
no limitations
Use constraints
license License
Other constraints
Open Government Licence v3.0
Use constraints
otherRestrictions Other restrictions
Other constraints
Data supplied under Open Government Licence v3.0
Use constraints
otherRestrictions Other restrictions
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None
Unique resource identifier
url
Codespace
url
Association Type
crossReference Cross reference
Unique resource identifier
doi
Codespace
doi
Association Type
crossReference Cross reference
Spatial representation type
textTable Text, table
Metadata language
engEnglish
Character set
utf8 UTF8
Topic category
  • Climatology, meteorology, atmosphere
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Begin date
2022-01-22
End date
2022-02-03
Supplemental Information
It is recommended that careful attention be paid to the contents of any data, and that the author be contacted with any questions regarding appropriate use. If you find any errors or omissions, please report them to polardatacentre@bas.ac.uk.
Date (Publication)
2008-11-12
Publisher
  European Petroleum Survey Group
https://www.epsg-registry.org/
Unique resource identifier
urn:ogc:def:crs:EPSG::3031
Version
6.18.3

Distributor

Distributor
  NERC EDS UK Polar Data Centre
British Antarctic Survey, High Cross, Madingley Road , Cambridge , Cambridgeshire , CB3 0ET , United Kingdom
+44 (0)1223 221400
https://www.bas.ac.uk/team/business-teams/information-services/uk-polar-data-centre/
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2621440
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Get Data ( WWW:LINK-1.0-http--link )

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dataset Dataset
Statement

Methodology:

The nitrous acid (HONO) amount fraction was measured at 1 minute resolution using a Long Path Absorption Photometer (LOPAP). Data has been processed to remove interferences and account for time delays in the instrument. Regular baseline measurements (blanks) and calibrations were carried out and have been applied to the data; the blanks and calibration periods have been removed from the dataset. The HONO amount fraction is given in pmol mol-1. The inlet height column relates to the height of the inlet of the LOPAP above the snow. A value of 0 represents inlet in transit and we recommend ignoring this data. The temperature measurements were collected at 1.26 and 0.05 m above the snow surface (indicated in column headings). The data was collected at 5 second intervals and are given in oC. U and V wind vectors were collected at 1 m above the snow at 5 second intervals and are given in ms-1. The temperature and wind data were collected to allow calculation of the HONO flux from the snow by the flux gradient method. All times are UTC.

Data collection:

Instruments:

a. HONO: LOng Path Absorption Photometer (LOPAP, QUMA Elektronik & Analytik GmbH)

b. Wind: Gill Wind Observer 70

c. Temperature: TME Ethernet Thermometer

Data quality:

HONO: During the campaign the LOPAP was calibrated every 5 days using nitrite solutions of known concentration (2 x 10^-3 and 8 x 10^-4 mg L-1). The gas flow rate was set to 2 L min-1 (298 K, 1 atm) with the internal mass flow controller and checked frequently using a flow meter (DryCal DC-Lite), and the liquid flow rate through the stripping coil for each channel was regularly measured volumetrically and was between 0.15 and 0.18 mL min-1 during the measurement period. Baseline measurements were made every 6 hours using a flow of pure nitrogen (99.998 %, BOC) at the instrument inlet. The detection limit (3 sigma-blank) was 0.26 pmol mol-1 for the measurement period. Any missing values and gaps in the time series correspond to blanks and calibrations that have now been removed from the dataset.

Wind and temperature: data has not been calibrated. Missing values are caused by issues with the instruments/data collection.

File identifier
94b2f348-d6cc-4bcd-b921-5c0928ab3c2d XML
Metadata language
engEnglish
Character set
utf8 UTF8
Hierarchy level
dataset Dataset
Hierarchy level name
dataset
Date stamp
2023-03-10
Metadata standard name
ISO 19115 Geographic Information - Metadata
Metadata standard version
ISO 19115:2003(E)
Point of contact
  NERC EDS UK Polar Data Centre
British Antarctic Survey, High Cross, Madingley Road , Cambridge , Cambridgeshire , CB3 0ET , United Kingdom
+44 (0)1223 221400
https://www.bas.ac.uk/team/business-teams/information-services/uk-polar-data-centre/
 
 

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Keywords

atmospheric chemistry nitrous acid reactive nitrogen trace gas
GEMET - INSPIRE themes, version 1.0
Atmospheric conditions
Global Change Master Directory (GCMD) Science Keywords
EARTH SCIENCE > Atmosphere > Atmospheric Chemistry EARTH SCIENCE > Atmosphere > Atmospheric Chemistry > Trace Gases/Trace Species EARTH SCIENCE > Atmosphere > Atmospheric Chemistry/Nitrogen Compounds

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